milldog said:
right if you were on a dive to 85 meters on a new wreck 25 minutes into it and you come across a sealed room in the wreck which has air trapped there, big enough area to get out of the water altoghather and sit there, so the question is
a, would you need to do decompression before going into that area
No because - as others have stated - the air trapped inside the wreck would be at ambient pressure unless, of course, it's sealed inside a totally water-tight bulk head. The problem there is that unless there's an intermediate air lock that allows you to balance the pressure difference, opening the door into the air-tight area would cause water to rush in!
milldog said:
b, as it was air from the surface would it be safe to breath and not flip out?
I don't honestly think that oxtox would be the problem here and anyway, why would getting an oxygen hit be a problem in a dry environment? Don't forget that the bit that kills you with an oxtox incident is usually not the oxygen hit itself - it's the fact that you usually spit out your reg and drown!
The other thing to consider is that the inside of the wreck is probably a) made of metal and b) damp so my guess is that the oxygen content of the air would actually drop over a long period of time as the oxygen reacts with the metal, causing corrosion. This is part of the reason why some training agencies used to warn divers to be careful about leaving fills in cylinders for long periods of time - if the cylinder contained any entrained water vapour, it was believed that it could cause a drop in the oxygen content of the gas inside the cylinder due to a corrosive reaction with the metal walls of the cylinder. In truth, the drop in oxygen contact is so small that it'll hardly register. For a wreck that may have been down there for a long period of time, though, it's a possibility, I guess.
Then, of course - as others have alluded to - you've got the problem of CO2 build up. Each time you breathe out into that environment, you're increasing the CO2 content which is going to continue to rise unless it's artificially 'scrubbed' using a scrubber like those found in a submarine or, for that matter, a rebreather. As Okeanos stated, there's also the other noxious gases to worry about - all that gas that's given off by decomposition/chemical reaction has to go somewhere! Yuk!
